The energy of a graph, if it is integral.
The energy of a graph is the sum of the absolute values of its eigenvalues. This statistic is only defined for graphs with integral energy. It is known, that the energy is never an odd integer [2]. In fact, it is never the square root of an odd integer [3].
The energy of a graph is the sum of the energies of the connected components of a graph. The energy of the complete graph $K_n$ equals $2n-2$. For this reason, we do not define the energy of the empty graph.

Sends a permutation to its reverse.
The reverse of a permutation $\sigma$ of length $n$ is given by $\tau$ with $\tau(i) = \sigma(n+1-i)$.

The graph of inversions of a permutation.
For a permutation of $\{1,\dots,n\}$, this is the graph with vertices $\{1,\dots,n\}$, where $(i,j)$ is an edge if and only if it is an inversion of the permutation.

The Simion-Schmidt map sends any permutation to a $123$-avoiding permutation.
Details can be found in [1].
In particular, this is a bijection between $132$-avoiding permutations and $123$-avoiding permutations, see [1, Proposition 19].