The largest eigenvalue of a graph if it is integral.
If a graph is $d$-regular, then its largest eigenvalue equals $d$. One can show that the largest eigenvalue always lies between the average degree and the maximal degree.
This statistic is undefined if the largest eigenvalue of the graph is not integral.

The de-duplicate of a graph.
Let $G = (V, E)$ be a graph. This map yields the graph whose vertex set is the set of (distinct) neighbourhoods $\{N_v | v \in V\}$ of $G$, and has an edge $(N_a, N_b)$ between two vertices if and only if $(a, b)$ is an edge of $G$. This is well-defined, because if $N_a = N_c$ and $N_b = N_d$, then $(a, b)\in E$ if and only if $(c, d)\in E$.
The image of this map is the set of so-called 'mating graphs' or 'point-determining graphs'.
This map preserves the chromatic number.

Sends a Dyck path $D$ with valley at positions $\{(i_1,j_1),\ldots,(i_k,j_k)\}$ to the unique non-crossing permutation $\pi$ having descents $\{i_1,\ldots,i_k\}$ and whose inverse has descents $\{j_1,\ldots,j_k\}$.
It sends the area St000012The area of a Dyck path. to the number of inversions St000018The number of inversions of a permutation. and the major index St000027The major index of a Dyck path. to $n(n-1)$ minus the sum of the major index St000004The major index of a permutation. and the inverse major index St000305The inverse major index of a permutation..

The graph of inversions of a permutation.
For a permutation of $\{1,\dots,n\}$, this is the graph with vertices $\{1,\dots,n\}$, where $(i,j)$ is an edge if and only if it is an inversion of the permutation.