The distinguishing index of a graph.
This is the smallest number of colours such that there is a colouring of the edges which is not preserved by any automorphism.
If the graph has a connected component which is a single edge, or at least two isolated vertices, this statistic is undefined.

The graph of inversions of a permutation.
For a permutation of $\{1,\dots,n\}$, this is the graph with vertices $\{1,\dots,n\}$, where $(i,j)$ is an edge if and only if it is an inversion of the permutation.

Krattenthaler's bijection to 321-avoiding permutations.
Draw the path of semilength $n$ in an $n\times n$ square matrix, starting at the upper left corner, with right and down steps, and staying below the diagonal. Then the permutation matrix is obtained by placing ones into the cells corresponding to the peaks of the path and placing ones into the remaining columns from left to right, such that the row indices of the cells increase.

The de-duplicate of a graph.
Let $G = (V, E)$ be a graph. This map yields the graph whose vertex set is the set of (distinct) neighbourhoods $\{N_v | v \in V\}$ of $G$, and has an edge $(N_a, N_b)$ between two vertices if and only if $(a, b)$ is an edge of $G$. This is well-defined, because if $N_a = N_c$ and $N_b = N_d$, then $(a, b)\in E$ if and only if $(c, d)\in E$.
The image of this map is the set of so-called 'mating graphs' or 'point-determining graphs'.
This map preserves the chromatic number.