The second largest eigenvalue of a graph if it is integral.
This statistic is undefined if the second largest eigenvalue of the graph is not integral.
Chapter 4 of [1] provides lots of context.

The threshold graph corresponding to the composition.
A threshold graph is a graph that can be obtained from the empty graph by adding successively isolated and dominating vertices.
A threshold graph is uniquely determined by its degree sequence.
The Laplacian spectrum of a threshold graph is integral. Interpreting it as an integer partition, it is the conjugate of the partition given by its degree sequence.

The de-duplicate of a graph.
Let $G = (V, E)$ be a graph. This map yields the graph whose vertex set is the set of (distinct) neighbourhoods $\{N_v | v \in V\}$ of $G$, and has an edge $(N_a, N_b)$ between two vertices if and only if $(a, b)$ is an edge of $G$. This is well-defined, because if $N_a = N_c$ and $N_b = N_d$, then $(a, b)\in E$ if and only if $(c, d)\in E$.
The image of this map is the set of so-called 'mating graphs' or 'point-determining graphs'.
This map preserves the chromatic number.

The complement of a graph.
The complement of a graph has the same vertices, but exactly those edges that are not in the original graph.